Buses start running from the resorts to the parks by 6:30am every day. They tend to run a bit less frequently until an hour before park opening, so plan accordingly. If you just miss a bus, you may have to wait at least 20+ mins for the next one.
To get from Pop to 'Ohana, I would get the MK bus as early as needed, then hop on the monorail, over to the Polynesian. The monorail starts running at 7am.
No resort buses go to the TTC.