The best stop is Pocohontas and her Forest Friends in Animal Kingdom - a cute show evn if you aren't a Pocohontas fan. Otherwise, just ask a CM to call guest relations as to whatever park you are in (or ask the concierge at your resort), and they will tell you where and when she will be appearing.
Last two trips we took she was at Rafikis planet watch taking photos and signing autographs. She is my daughter's absolute favorite (next to Kim Possible!!)
On our last trip in November, we saw Pocahontas by the entrance to MGM (right after you enter through the turnstiles) on a couple of different days. We usually saw her out greeting inbetween 11:00ish and 2:30ish, on half-hour intrevals. We also saw her at Magic Kingdom to the left of the Castle (if facing it), on a sidewalk inbetween the main sidewalks into Adventureland and Liberty Square. Hard to describe location! I never seen her there before, so not sure if it's a constantly used location.
As another poster said, you can always ask at Guest Services. For well-known characters like Pocahontas, they should be able to check for her. Hope your DD gets to meet her!
We saw Pochohantas in MK twice. My DD was THRILLED. She was behind the Christmas Shop in Liberty Square...there is a little "park" there... very out of the way!!
We saw her at MK, behind the Christmas store. We also saw Wendy at the Pirates of the Carribean. Wendy told me to ask a cashier to find out the exact time to see Pochohantas. She showed up at 2:00pm and we were 2nd to see her, not many people knew she was there. I see only 3 more days til you go, dallastxcpa.
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