Absolutely!
I wanted pictures of identifiable "Disney" locations for our pictures, so we planned our wedding schedule around having a break between our wedding and our wedding luncheon to allow for this.
We did an Escape wedding, and had the 9:00 a.m. slot at the Wedding Pavilion. We had the limo pick us up at Shades of Green at 8:00, then had it pick up the rest of our guests at the Wilderness Lodge (we had them all park there, since that was where we were going to end the day).
We had our cake and champagne reception over at the Grand Floridian, and we took the limo over there from the Wedding Pavilion. We then still had the limo until 11:00 a.m. We made sure we left our reception by 10:40 so we would have time to get to the limo and have him take us to Epcot before time ran out. All our guests (except my sister, who was MOH, and her husband - they went with us) were told they had until 2:00 p.m. to change clothes, wander around, and use the boats to go back to the Wilderness Lodge for lunch.
We then proceeded on our wedding photography odyssey across Disney. Our photographer, Misty, took lots of photos everywhere we went. We stopped for posed photos, and she also just snapped a lot while we were walking or waiting for transportation.
We got pictures outside of Epcot, then took the monorail over to the TTC. From there, we took the ferry to the MK, and got pictures outside of there. We then took the monorail around to the Poly and got pictures there. From there, we took the boat back to the MK, and then the boat to the WL (I didn't know enough about the boat routes then, or we would have gotten back on the monorail to the Contemporary and gotten the boat to WL from there!) Our lunch reservations were for 2:00 p.m. We were actually late - about 2:20 or 2:30. I think the planning was all good - if we'd taken the monorail instead of the boat from the Poly, I think we would have been fine on time.
And we were all VERY happy with the pictures. I don't have a lot of them up - I've only managed to get a few that kind of track our journey up on my web page. But if you want to see, go to kims-world.net and go to the wedding section.
BTW - note that we had an outside photographer who was very enthusiastic about getting shots in different locations around the parks. If you use DPS, I don't know if they will do any of this. You can ask - we had already decided on Misty before we decided on where we wanted shots, so we never checked with DPS if they would be willing to do any of that. I don't know if they would or wouldn't do different locations like that. We didn't bother asking, we just went.