Doesn't really make a difference. By that time of the day, crowds will be pretty equally disbursed. If you want to see all the live entertainment, you might want to check an entertainment schedule and plan your way around accordingly!
...but seriously, we do Mexico to Canada usually. I know that by late afternoon it doesn't matter as much, but I still think that the majority of people entering the WS enter in Canada, so you avoid a little maybe.
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