The best is Canyon Ranch at the Gaylord--World Class in every respect.
After that my next choice would be Mandara Spa at the Dolphin.
Both of those will give you a very memorable spa experience that is heads and shoulders above anything you'll get at any of the Nikki Bryan run Disney Spas, which IMHO are highly over rated and over priced for the level of service and quality of products they use. (Nikki Bryan is no longer using Jurlique as an FYI to anyone reading this who uses those products.)