What does a successful first 90 days look like for this position? This is a way to ask about the top pain points and allows the interviewer to discuss first priorities once initial training is done.
Is this a new position or am I filling an opening due to someone leaving or being promoted? This may be obvious depending on the position but if it is for an analyst role, a support role, or any implementation position it would be good to know. If it is a new role follow up with what prompted the role to be created.