Yes you can pick up a times guide as you enter the parks. It will list show times, attraction times, charecter greetings, etc. They do no list everything but it's a pretty good start. If you want to see the info beforehand you can check out Steve Soares WDW Entertainment site, he updates it weekly with the info from the times guide.
I would be glad to email you the cards I use to keep up with all of the show times, parade times, character times, etc... just pm me if interested, or pop over to the DISigns board.
is the one I look at ahead of time. For locations, the following link is a great site that's maintained by someone that frequents these boards. From what I can see it is well maintained. The park maps with character locations seems to be what you're looking for.
As mentioned above time are for major character meet and greets. Places like the Animation Courtyard will have a variety of characters.
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