I go to DLR at least once a week, and I would grab a Soarin' FP on my way to TSMM. Ride that and Screamin', which generally has a less than 10 minute wait that early. Your Soarin' FP should be return between 40 min after RD and 1hr40min after RD. At RD+40 min, get RSR FP, you won't wait at all and should get an early afternoon return. Ride other Paradise Pier rides until near end of Soarin' return time, ride Soarin' and other non-FP rides until can get new FP (get as soon as window opens), which should be about RD+2hr 40 min, if you got it as soon as FP window opened up. At this point either get ToT FP or GRR FP depending on when park opened, and how hot it is.
So in summary, assuming RD is 8 am. Arrive by at least 7:45 and line up by Soarin', grab FP and take GRR trail to TSMM. Ride TSMM and Screamin'. May have time for Fun Wheel. Send runner to get RSR FP at 8:40 (will be able to get another 2 hours later) for an early afternoon return, join group at Paradise Pier, ride swings, Goofy, Maters...until 9:30. Arrive at Soarin' around 9:30 to ride with FP. Ride other non-FP rides, Monsters, Ariel... until 10:40 when you'll be able to get another FP. Get ToT FP, which should have a return around 11:30 or 12, get GRR FP as soon as window opens, ride other non-FP rides until near end of ToT FP window, ride ToT, do other Hollywood attractions and ride RSR and GRR in the afternoon with FP. That's what I would do, but I would also encourage you if at all possible to go to DCA on a non EE day unless you can utilize it.