Yes.
If you call MS to order the passes, they may not know what the DVA is. If they are confused about the DVA, tell them it's a Disney Gift Card (since that's basically how the DVA works).
If your
DVC information is linked to your
MDE profile, the on-line order process at disneyworld.com will let you use the DVA. The payment option is Disney Gift Card or Disney Vacation Account.