There is an 800 # I think it is 800 Disney4U but I am not sure. Call and you can get the card over the phone. The Disney Club Website doesn't work well for me. I doubt that you can purchase the card at the Disney store although from a marketing standpoint it makes sense.
The Disney Club application forms are available there, but not the actual cards. Those are sent to you via snailmail once your application is processed.
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