I am not a NC lawyer however I did a quick look at the North Carolina General Statutes covering divorce (Chapter 50). I find no prohibition to acting as your own attorney (pro se is the term).
Here is a link to Chapter 50:
http://www.ncga.state.nc.us/enactedlegislation/statutes/html/bychapter/chapter_50.html
It is a common practice for the employees of courts to not give out any legal advice whatsoever.
I actually have no qualms about your daughter doing her own divorce. A plain vanilla divorce is very simple. If she appears in front of the judge and he or she finds some problem with the papers, he or she will usually tell her what she has to do to correct it.
File the petition for divorce, containing the language mandated by Chapter 50 (residency, no children, etc).
The husband must be served notice. I imagine that either your daughter will pay the fee to have him served in prison or, if NC allows, she may mail him a notice and have him sign and return for submission to the court.
Here is another link to information that may prove helpful form the North Carolina Family Law Center:
http://www.divorcelawinfo.com/states/nc/northcarolina.htm
One of their statements: It is not advisable to represent yourself if you have a contested custody matter, you have substantial property, or there is a dispute over pension rights. Self-representation is a process that works best for those with routine and uncontested legal matters and for those who can master the steps necessary to get from filing the complaint through the final hearing.
An example is an uncontested divorce or a child support modification where the child support obligation for each parent is determined by statute. (emphasis mine)
I hope this helps some.