On deluxe, we were typically eating 3 meals a day, the vast majority were TS. We booked our ADRs around what we wanted our schedule to be, rather than book a whole bunch of ADRs and then trying to make a schedule around them.
So, we booked the character breakfasts first. Based on where they were, we planned our park days accordingly, adding in lunches (some days) and dinner to complement the schedule we were creating.
The other important part was time. The breakfasts were (except for CRT) all early enough to put us into the parks after eating earlier than 9:30. (For CRT, we actually went into the park and then had breakfast after a quick ride and fastpass run.) Lunches were booked for as close to noon as possible, which was right when the kids would need a break and want to eat. Dinners were booked as close to 6 PM as possible, for similar reasons.
Our touring plans were then made to match our ADRs. In DHS, for example, with a lunch at Mama Melrose, we made our way over to do Muppets 3D and the meet-and-greet with Lightning McQueen in the late morning, which put us right at MM at ADR time. On our MK days, we picked which section(s)of the park to focus on each day based on our schedule; e.g., for a Liberty Tree Tavern lunch day, we hung out in Adventureland and Fronteirland, so we only had a couple minutes walk to LTT when it was time.