Sadly, we too were not able to book anything Palo beyond dinner on the first sea day. But you must also remember that they don't open everything up online.
DCL does save a number of reservation times for booking onboard. This could simply be a rare instance where every single concierge guest booked brunch and tea and ate up most of the online availability.
As far as Barcelona goes, after being told several times that the excursions I wanted to do prior to embarkation must be full, I finally got the REAL answer. May 25 and Aug 19 excursions are intended for transatlantic guests (which is what I figured since Barcelona is a port day for them). You may be able to add on to those once you arrive at your hotel. Check with the excursion desk there.
If you are staying at a Disney-booked hotel prior to the cruise, you can do excursions that say "One Day Prior," "Two Days Prior," etc. But you can't book them online. Only "Embarkation Day" excursions are available to us on the website. You need to call the excursion company directly for anything prior. Here's the info:
Phone: 0034902102877 (don't forget your intl extenstion if necessary)
Email:
barcelonaexcursions@ultramarexpress.com
This is the vendor Disney is using in Barcelona. I would have been surprised if this HAD been available online since it would have required cross-checking to confirm your pre-cruise stay, and that seemed kinda complicated for the website. (I know it can be done, but DCL doesn't always do complicated computer things well, as we've all seen)
We're probably just going to do our own excursions in Barcelona anyway, but wanted to share the info in case anyone else needed it. We usually stick with DCL excursions for the simplicity and safety of getting back to the ship, but we have more flexibility in Barcelona.
Here are the other things we have booked:
Palermo: Erice and Segesta
Naples: Timeless Pompeii and the Flavor of Sorrento
Olbia: Gnocchetti Sardi and Ravioli
Civitavecchia: Jumping Back into Eternal Rome
La Spezia: Wine Tasting and Sarzana
Marseille: Chateau Neuf Du Pape and Avignon
Villefranche: Nice and Eze with Wine and Cheese
Plus all our spa appointments on sea day mornings.
Jen