Unfortunately, you don't find many villains around the parks...the usual ones are Gaston, Lady Tremaine & Step sisters
and Hook (with Smee sometimes). DS loves villains and we go to
MNSSHP just to see them. He's even disappointed in the new 3:00 parade as there are hardly any villains..in the previous parade towards the end there were a bunch of characters walking which included Jafar, Queen of Hearts, John Longfellow and others. If you go to Pirate Kenny's website he talks about Characterpalooza in DHS. It's an unscheduled event, but usually during a certain time of day on Streets of America (depending upon Fantasmic schedule) characters just show up for meet and greets...You may get to see a Villain then..it's a shot in the dark. One time during characterpalooza (when it was in Animation building) DS got to see Evil Queen..he was thrilled - we took a picture and he got her autograph. We are definitely among the list of people who wish there were more Villains to be seen in the parks.